TY - JOUR A1 - Fenske, Dieter A1 - Adel, Jörg A1 - Dehnicke, Kurt T1 - Die Kristallstruktur von Bis(η-cyclopentadienyl)titana(Ti,IV)- cyclohexaselenan, Cp2TiSe5 T1 - The Crystal structure of Bis(η-cyclopentadienyl)titana(Ti,IV)- cyclohexaselenane, Cp2TiSe5 T2 - Zeitschrift für Naturforschung, B N2 - Cp2TiSe5 has been prepared by the reaction of trim ethyltetradecylammonium-polyselenide with Cp2TiCl2 in ethanol solution and subsequent extraction of the dry residue with dichloromethane. Cp2TiSe5 crystallizes in the space group P1 with two formula units in the unit cell (2559 observed, independent reflexions, R = 0.074). The cell dimensions are a = 808.6, b = 822.6, c = 1190.7 pm, α - 96.28°, β - 106.06°, γ = 108.78°. The structure consists of discrete Cp2TiSe5 molecules with the TiSe5, ring in the chair conformation. KW - Bis(η-cyclopentadienyl)titana(TiIV)cyclohexaselenane KW - Synthesis KW - Crystal Structure Y1 - 2014 UR - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/79962 UR - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-799626 SN - 1865-7117 SN - 0932-0776 VL - 42.1987 IS - 4 SP - 931 EP - 933 PB - Verlag der Zeitschrift für Naturforschung CY - Tübingen ER -