TY  - JOUR
A1  - Kinauer, Markus
A1  - Diefenbach, Martin
A1  - Bamberger, Heiko
A1  - Demeshko, Serhiy
A1  - Reijerse, Edward J.
A1  - Volkmann, Christian
A1  - Würtele, Christian
A1  - Slageren, Joris van
A1  - Bruin, Bas de
A1  - Holthausen, Max C.
A1  - Schneider, Sven
T1  - An iridium(III/IV/V) redox series featuring a terminal imido complex with triplet ground state
T2  - Chemical science
N2  - The iridium(III/IV/V) imido redox series [Ir(NtBu){N(CHCHPtBu2)2}]0/+/2+ was synthesized and examined spectroscopically, magnetically, crystallographically and computationally. The monocationic iridium(IV) imide exhibits an electronic doublet ground state with considerable ‘imidyl’ character as a result of covalent Ir–NtBu bonding. Reduction gives the neutral imide [Ir(NtBu){N(CHCHPtBu2)2}] as the first example of an iridium complex with a triplet ground state. Its reactivity with respect to nitrene transfer to selected electrophiles (CO2) and nucleophiles (PMe3), respectively, is reported.
Y1  - 2018
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/46511
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-465113
SN  - 2041-6539
SN  - 2041-6520
N1  - This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
VL  - 9
IS  - 18
SP  - 4325
EP  - 4332
PB  - RSC
CY  - Cambridge
ER  -