TY  - JOUR
A1  - Fenske, Dieter
A1  - Ohmer, Johannes
A1  - Merzweiler, Kurt
T1  - Darstellung und Kristallstrukturen von [Co6Se8(PPh3)6]+[CoCl3(THF)]¯ , [Co8Se8(PPh3)6][Co6Se8(PPh3)6] und [Co8Se8(PPh3)6]+[CoCl3(PPh3)]¯
T1  - Synthesis and crystal structures of [Co6Se8(PPh3)6]+[CoCl3(THF)]¯ , [Co8Se8(PPh3)6][Co6Se8(PPh3)6] und [Co8Se8(PPh3)6]+[CoCl3(PPh3)]¯
T2  - Zeitschrift für Naturforschung, B
N2  - (NBu4)[CoCl3(PPh3)] reacts with Se(SiMe3)2 to form the new clusters [Co8Se8(PPh3)6][CoCl3(PPh3)] (6) and [Co8Se8(PPh3)6][Co6Se8(PPh3)6] (7). The structures of 6 and 7 have been determ ined by X-ray diffraction. 6 and 7 crystallize in the space group P1̄ with two formula units per unit cell and with the following lattice constants at 180 K: 6: a = 1413.8(10), b - 2224.2(23), c = 2348.4(17) pm, α = 86.06(5), β = 86.58(5), γ = 76.11(5)°; 7: a = 1465.9(4), b = 1627.6(6), c = 2505.7(6) pm, α - 98.69(2), β = 96.23(2), γ = 113.06(2)°. The cluster structures of the [Co8Se8(PPh3)6]n (n = 0, 1 +) depend on the total number of electrons in the cluster units.
KW  - X-Ray
KW  - Crystal Structure of [Co8Se8(PPh3)6]n (n = 0; 1+)
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/79985
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-799853
SN  - 1865-7117
SN  - 0932-0776
VL  - 42.1987
IS  - 7
SP  - 803
EP  - 809
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -