TY  - JOUR
A1  - Görge, Astrid
A1  - Dehnicke, Kurt
A1  - Fenske, Dieter
T1  - N-Chlornitrenokomplexe des Wolframs: WCl4(NCl) und [CH3CN-WCl4(NCl)]
T1  - N-chloro-nitrene complexes of tungsten: WCl4(NCl) and [CH3CN-WCl4(NCl)]
T2  - Zeitschrift für Naturforschung, B
N2  - WCl4(NCl) has been prepared as a red-brown crystal powder by the reaction of tungsten hexacarbonyl with excess nitrogen trichloride in boiling CCl4. The complex is associated via chloro bridges, forming dimeric units, according to the IR spectrum. Thermal decomposition at 200 °C leads to tungsten nitride trichloride, WNCl3,. With acetonitrile, WCl4(NCl) reacts with formation of the monomeric complex [CH,CN-WCl4(NCl)], which was characterized by its IR spectrum as well as by an X-ray structure determination. Crystal data: space group P21/m, Z = 2 (1387 independent observed reflexions, R = 0.07). Lattice dimensions at 20 °C: a = 590.4(3), b = 729.0(3), c = 1124.6(4) pm, β = 100.63(2)°. The complex forms monomeric molecules, in which the tungsten atom has a distorted octahedral environment of four chlorine atoms in equatorial positions, and the acetonitrile molecule in trans-position to the  group. Bond lengths WN = 172 and NCI = 161 pm; bond angle WNCl = 175.5°.
KW  - Synthesis
KW  - IR Spectra
KW  - X-Ray
KW  - N-Chloro-Nitrene-Tungsten Tetrachloride
KW  - Acetonitrile Adduct
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/71434
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-714344
SN  - 1865-7117
SN  - 0932-0776
VL  - 43.1988
IS  - 6
SP  - 677
EP  - 681
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -