TY  - JOUR
A1  - Wittel, Klaus
A1  - Astrup, Eva Elisabeth
A1  - Bock, Hans
A1  - Graeffe, Gunnar
A1  - Juslén, Heikki
T1  - Photoelectron spectra and molecular properties, XLVIII. Carbonates and thiocarbonates
T2  - Zeitschrift für Naturforschung, B
N2  - Photoelectron (PE) spectra of ethylene and vinylene carbonates and thiocarbonates as well as of methylene trithiocarbonate and some open-chain derivatives are reported.
The low energy bands, well separated in the unsaturated compounds, are assigned to lone pair and π type ionizations. The assignment is based on comparison of PE spectra, modified CNDO calculations, and sulfur Κβ emission spectra. The pronounced substituent effects due to which the first ionization potential varies from 8.4 eV to 11.1 eV are discussed.
KW  - Photoelectron
KW  - X-ray
KW  - Carbonates
KW  - Thiocarbonates
KW  - MO Calculations
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/76153
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-761537
SN  - 1865-7117
SN  - 0932-0776
VL  - 30.1975
IS  - 11-12
SP  - 862
EP  - 874
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -