TY - JOUR A1 - Konopka, Paul A1 - Günther, Gebhard A1 - Müller, Rolf A1 - Santos, Fábio Henrique Silva dos A1 - Schiller, Cornelius A1 - Ravegnani, Fabrizio A1 - Ulanovsky, Alexey A1 - Schlager, Hans A1 - Volk, C.-Michael A1 - Viciani, Silvia A1 - Pan, Laura L. A1 - McKenna, Daniel-S. A1 - Riese, Martin T1 - Contribution of mixing to the upward transport across the TTL T2 - Atmospheric chemistry and physics / Discussions N2 - During the second part of the TROCCINOX campaign that took place in Brazil in early 2005, chemical species were measured on-board of the high altitude research aircraft Geophysica (ozone, water vapor, NO, NOy, CH4 and CO) in the altitude range up to 20 km (or up to 450 K potential temperature), i.e. spanning the TTL region roughly extending between 350 and 420 K. Analysis of transport across TTL is performed using a new version of the Chemical Lagrangian Model of the Stratosphere (CLaMS). In this new version, the stratospheric model has been extended to the earth surface. Above the tropopause, the isentropic and cross-isentropic advection in CLaMS is driven by ECMWF winds and heating/cooling rates derived from a radiation calculation. Below the tropopause the model smoothly transforms from the isentropic to hybrid-pressure coordinate and, in this way, takes into account the effect of large-scale convective transport as implemented in the ECMWF vertical wind. As with other CLaMS simulations, the irreversible transport, i.e. mixing, is controlled by the local horizontal strain and vertical shear rates. Stratospheric and tropospheric signatures in the TTL can be seen both in the observation and in the model. The composition of air above ≈350 K is mainly controlled by mixing on a time scale of weeks or even months. Based on CLaMS transport studies where mixing can be completely switched off, we deduce that vertical mixing, mainly driven by the vertical shear in the outflow regions of the large-scale convection and in the vicinity of the subtropical jets, is necessary to understand the upward transport of the tropospheric air from the main convective outflow around 350 K up to the tropical tropopause around 380 K. This mechanism is most effective if the outflow of the mesoscale convective systems interacts with the subtropical jets. Y1 - 2006 UR - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/29268 UR - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-292685 SN - 1680-7367 SN - 1680-7375 N1 - © Author(s) 2006. This work is licensed under a Creative Commons License. VL - 6 SP - 12217 EP - 12266 PB - European Geosciences Union CY - Katlenburg-Lindau ER -