TY  - JOUR
A1  - Chun, Hans-Ulrich
A1  - Hendel, Dieter
T1  - Röntgenspektroskopische Untersuchung der chemischen Bindung in Oxiden
T2  - Zeitschrift für Naturforschung, A
N2  - This paper reports about the fine structure in the O—K-spectra of the oxides BeO, MgO, CaO, SrO, BaO, Sc2O5, Y2O3, La2O3, Sm2O3, Yb2O3, NiO and ZnO. The spectra show the satellite lines α3, α4, α5, α6 on the short wavelength side of the main line α1,2 and a shoulder β′ on its long wavelength side. The wavelengths of all lines depend on the nature of the oxide. For the positions of the lines Kα1.2 in the spectra no systematic relation to other data of the oxides is observed. On the other hand the distance of the a4-satellite from the α1,2-line decreases with increasing electronegativity of the metal atom in the oxide. This distance can be used as a measure for the ionic character of the metal-oxygen bond in these compounds.
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/74208
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-742086
SN  - 1865-7109
VL  - 22
IS  - 9
SP  - 1401
EP  - 1407
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -