TY  - JOUR
A1  - Roesky, Herbert W.
A1  - Petersen, Olaf
T1  - Phosphor- und Schwefelhydrazin-Verbindungen
T1  - Phosphorus- and sulfurhydrazine-compounds
T2  - Zeitschrift für Naturforschung, B
N2  - Pyrosulfonyldifluoride reacts with waterfree hydrazine in a molar ratio of 2 : 3 to give hydrazine -1,2-bis(sulfonylfluoride) in a low yield.. The reaction of N-fluorosulfonylamide and SOCl2 yields NH4⊕⊖ N(SO2F)2. This salt is converted to (C6H5)4P⊕⊖N(SO2F)2 in water by (C6H5)4PCl. (CH3)2NNH2 reacts with PSF3, PSF2Br, PSF2CH3 or PSF2C2H5 to yield the following compounds: (CH3)2NNHPSF2, (CH3)2NN (PSF2)2, (CH3)2NNHPSFCH3 and (CH3)2NNHPSFC2H5. The properties and the chemical behaviour of these substances are described. Results of ir-spectra, as well as 31P-, 19F- and 1H-nmr- and mass-spectra and elemental analysis characterize the compounds.
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/71488
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-714882
SN  - 1865-7117
SN  - 0932-0776
VL  - 26
IS  - 12
SP  - 1232
EP  - 1235
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -