TY  - JOUR
A1  - Herrmann, Wolfgang A.
A1  - Plank, Johann
A1  - Hubbard, John L.
A1  - Kriechbaum, Gangolf W.
A1  - Kalcher, Willibald
A1  - Koumbouris, Basile
A1  - Ihl, Gabriele
A1  - Schäfer, Adolf
A1  - Ziegler, Manfred L.
A1  - Pfisterer, Heike
A1  - Pahl, Claudia
A1  - Atwood, Jerry L.
A1  - Rogers, Robin D.
T1  - Übergangsmetall-Methylen-Komplexe, LI [1]. Carbocyclische Carbene, Carben-Brücken, kleine Kohlenwasserstoff-Liganden und Metallacyclen: Beispiele einer umfassenden Synthesekonzeption
T1  - Transition metal methylene complexes, LI [1]. Carbocyclic carbenes, carbene bridges, small hydrocarbon ligands, and metallacycles: examples of a general synthetic concept
T2  - Zeitschrift für Naturforschung, B
N2  - Carbene transfer from aliphatic diazoalkanes upon coordinatively unsaturated metal centers is a general synthetic concept that provides straight-forward routes into organo-metallic hydrocarbon chemistry. A comparison focussing on several key reactions of general applicability demonstrates that mononuclear organometal substrates add carbenes that may act as bridging ligands (e.g., compound 6) if they arise from ω,ω'-bisdiazoalkanes. By way of contrast, metal-metal double bonds cleanly form dimetallacyclo-propane-type derivatives under very mild conditions (7-9). The broadest variety of structures is finally encountered with metal-metal triply bonded precursors such as the molybdenum compounds 3: here, the initial diazoalkane adducts are subject to further rearrangement processes commonly leading to metal-metal single bonds (11) or causing irreversible cleavage of the dinuclear metal systems (10).
KW  - Carbene Transfer
KW  - Metal-Metal Multiple Bonds
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/71976
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-719765
SN  - 1865-7117
SN  - 0932-0776
VL  - 38.1983
IS  - 11
SP  - 1392
EP  - 1398
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -