TY  - JOUR
A1  - Tapmeyer, Lukas
A1  - Eisenbeil, Daniel
A1  - Bolte, Michael
A1  - Schmidt, Martin U.
T1  - First crystal structure of a Pigment Red 52 compound: DMSO solvate hydrate of the monosodium salt
T2  - Acta Crystallographica. Section E, Crystallographic communications
N2  - Pigment Red 52, Na2[C18H11ClN2O6S], is an industrially produced hydrazone-laked pigment. It serves as an inter­mediate in the synthesis of the corresponding Ca2+ and Mn2+ salts, which are used commercially for printing inks and lacquers. Hitherto, no crystal structure of any salt of Pigment Red 52 is known. Now, single crystals have been obtained of a dimethyl sulfoxide solvate hydrate of the monosodium salt of Pigment Red 52, namely, monosodium 2-[2-(3-carb­oxy-2-oxo-1,2-di­hydro­naphthalen-1-yl­idene)hydrazin-1-yl]-5-chloro-4-methyl­benz­ene­sulfonate dimethyl sulfoxide monosolvate monohydrate, Na+·C18H12ClN2O6S−·H2O·C2H6OS, obtained from in-house synthesized Pigment Red 52. The crystal structure was determined by single-crystal X-ray diffraction at 173 K. In this monosodium salt, the SO3− group is deprotonated, whereas the COOH group is protonated. The residues form chains via ionic inter­actions and hydrogen bonds. The chains are arranged in polar/non-polar double layers.
KW  - crystal structure determination
KW  - organic pigment
KW  - solvate
KW  - hydrate
Y1  - 2021
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/75791
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-757917
SN  - 2056-9890
VL  - 77
IS  - 4
SP  - 402
EP  - 405
PB  - International Union of Crystallography
CY  - Chester
ER  -