TY  - JOUR
A1  - Bock, Hans
A1  - Dammel, Ralph
A1  - DesMarteau, Darryl D.
T1  - Gasphasen-Reaktionen, 59 [1, 2]. Die Pyrolysen von Trifluormethylazid und Hexafluorazomethan
T1  - Gas phase reactions, 59 [1, 2]. The pyrolyses of trifluoromethylazide and hexafluoroazomethane
T2  - Zeitschrift für Naturforschung, B
N2  - Trifluoromethyl azide decomposes in a low-pressure flow system at rather high temperatures by splitting off N2. The nature of the resulting products depends largely on the wall material of the pyrolysis tube: using molybdenum above 1120 K, FCN is observed exclusively. Neither F2C=NF nor F3C-N=N-CF3 can be detected as intermediates by comparing their PE spectra with those continuously recorded while increasing the temperature. F3C-N = N - CF3 fragments already at 870 K to give N2 and F3C-CF3. The PE spectra of F3CN3 and F2C=NF are assigned based on MNDO calculations.
KW  - Trifluoromethylazide
KW  - trans-Hexafluoroazomethane
KW  - Perfluoromethanimine
KW  - Gas Phase Pyrolysis
KW  - PE Spectra
KW  - MO Calculations
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/79976
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-799767
SN  - 1865-7117
SN  - 0932-0776
VL  - 42.1987
IS  - 3
SP  - 308
EP  - 314
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -