TY  - JOUR
A1  - Brito, Iván
A1  - Szilágyi, László
A1  - Kumar, Ambati Ashok
A1  - Albanez, Joselyn
A1  - Bolte, Michael
T1  - 2-Phenyl­ethyl 1-thio-β-d-galactopyran­oside hemihydrate
T2  - Acta crystallographica / Section E, Structure reports online
N2  - The title compound, C14H20O5S·0.5H2O, crystallizes with two organic mol­ecules and a solvent water mol­ecule in the asymmetric unit. In both mol­ecules, the hexa­pyranosyl rings adopt a slightly distorted chair conformation (5 C 2) with four substituents in equatorial positions and one substituent in an axial position. The main difference between the organic mol­ecules is the dihedral angle between the phenyl ring and the best plane defined by the O—C1—C2—C3 atoms (r.m.s deviations = 0.003 and 0.043 Å) of the hexa­pyranosyl rings [47.4 (4) and 86.5 (4)°]. In the asymmetric unit, mol­ecules are linked by two strong O—H[cdots, three dots, centered]O hydrogen bonds. In the crystal, the components are linked by a total of 10 distinct O—H[cdots, three dots, centered]O hydrogen bonds, resulting in the formation of a two-dimensional network parallel to the ab plane.
Y1  - 2011
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/25302
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-253027
SN  - 1600-5368
VL  - 67
IS  - o2308–o2309
PB  - Munksgaard
CY  - Copenhagen
ER  -