TY  - JOUR
A1  - Teichtmeister, Tobias A.
A1  - Bayarjargal, Lkhamsuren
A1  - Heymann, Gunter
A1  - Huppertz, Hubert
T1  - High-pressure/high-temperature synthesis of the new boron-rich terbium hydroxyborate Tb3B12O19(OH)7
T2  - Solid state sciences
N2  - Monoclinic Tb3B12O19(OH)7 was obtained by multianvil high-pressure/high-temperature syntheses at 6 GPa and 650 °C. The crystal structure was investigated by single-crystal X-ray diffraction methods and space group C2 (no. 5) with the unit cell parameters a = 24.2299(5) Å, b = 4.4667(1) Å, c = 7.0964(2) Å, β = 94.58(1)°, and two formula units per cell were revealed. Powder X-ray diffraction, infrared spectroscopy and the investigation of its second harmonic generation properties support the proposed structural model.
KW  - Borate
KW  - Crystal structure
KW  - High-pressure
KW  - Solid-state chemistry
KW  - Terbium
Y1  - 2023
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/79689
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-796896
SN  - 1293-2558
VL  - 146
IS  - 107373
PB  - Elsevier
CY  - Amsterdam
ER  -