TY  - JOUR
A1  - Vitze, Hannes
A1  - Wietelmann, Ulrich
A1  - Murso, Alexander
A1  - Bolte, Michael
A1  - Wagner, Matthias
A1  - Lerner, Hans-Wolfram
T1  - Supersilyliertes Ethen trans-(tBu3Si)HC=CH(SitBu3) und Ethin (tBu3Si)C≡C(SitBu3)
T1  - Supersilylated ethene trans-(tBu3Si)HC=CH(SitBu3) and ethyne (tBu3Si)C≡C(SitBu3)
T2  - Zeitschrift für Naturforschung, B
N2  - The supersilylated ethene trans-(tBu3Si)HC=CH(SitBu3) (triclinic, P ī) is accessible from the reaction of tBu3SiCHBr2 with nBuLi at −78 °C in THF or Et2 O. The reaction of Li(H2NCH2CH2NH2)C≡CH with tBu3SiBr leads to the formation of (tBu3Si)C≡CH and (tBu3Si)C≡C(SitBu3). X-Ray quality crystals of (tBu3Si)C≡C(SitBu3) (triclinic, P ī) were obtained by recrystallization from hexane. In contrast to the structures of the disilane tBu3Si-SitBu3 and the disiloxane tBu3Si-O-SitBu3, the sterically crowded ethene trans-(tBu3Si)HC=CH(SitBu3) and ethyne (tBu3Si)C≡C(SitBu3) feature dihedral angles of 60° in the solid-state structures.
KW  - Ethene
KW  - Ethyne
KW  - Supersilyl
KW  - Carbene
KW  - Crystal Structure Analysis
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/80733
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-807336
SN  - 1865-7117
SN  - 0932-0776
VL  - 64.2009
IS  - 2
SP  - 223
EP  - 228
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -