TY - JOUR A1 - Bock, Hans A1 - Hierholzer, Bernhard A1 - Jaculi, Dieter T1 - Elektronentransfer und Ionenpaar-Bildung, 8 [1]. 107,109Ag ENDOR-Kopplungen und Redox-Verhalten des Radikal-Kontaktionenpaares aus Bis(triphenyIphosphino)silber(I)-Kation und 3,5-Di(tert-butyl)-o-benzosemichinon-Anion T1 - Electron transfer and ion pairing, 8 [1]. 107'109Ag ENDOR couplings and redox behaviour of the radical contact ion pair from bis(triphenylphosphino)silver(I) cation and 3,5-di(tert-butyl)-o-benzosemiquinone anion T2 - Zeitschrift für Naturforschung, B N2 - For the first time, 107,109Ag ENDOR measurements in solution are reported. In addition, the formation of the known paramagnetic contact ion pair [Ag⊕(PR3)2(R2H2C6O2·⊖] on reduction of 3,5-di(tert-butyl)-o-benzoquinone in THF solution containing soluble silver salts and triphenylphosphine is studied by cyclic voltammetry. KW - ENDOR Couplings KW - Cyclic Voltammetry KW - Contact Ion Pair [Ag⊕(PR3)2(R2H2C6O2·⊖)] Y1 - 2014 UR - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/66926 UR - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-669267 SN - 1865-7117 SN - 0932-0776 VL - 43.1988 IS - 10 SP - 1247 EP - 1252 PB - Verlag der Zeitschrift für Naturforschung CY - Tübingen ER -