TY  - JOUR
A1  - Lerner, Hans-Wolfram
A1  - Schödel, Frauke
A1  - Sänger, Inge
A1  - Wagner, Matthias
A1  - Bolte, Michael
T1  - Supersilylated tetrachlorodigermane (tBu3Si)Cl2GeGeCl2(SitBu3) and trigermoxetane (tBu3Si)3Ge3Cl3O
T2  - Zeitschrift für Naturforschung, B
N2  - In contrast to the tetrachlorodigermane (tBu3Si)Cl2Ge-GeCl2(SitBu3), the cis,transcyclotrigermane (tBu3SiGeCl)3 is sensitive to oxygen. Its treatment with O2 at ambient temperature leads to the trigermoxetane (tBu3Si)3Ge3Cl3O. According to an X-ray structure analysis of single crystals consisting of cocrystallized (tBu3Si)3Ge3Cl3O and (tBu3Si)Cl2Ge-GeCl2(SitBu3) the trigermaoxetane contains an almost planar Ge3O-ring while the tetrachlorodigermane (tBu3Si)Cl2Ge- GeCl2(SitBu3) possesses a Si-Ge-Ge-Si chain which is exactly all trans,
KW  - Supersilyl
KW  - Germane
KW  - Germoxane
KW  - X-Ray Structure Analysis
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/80643
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-806436
SN  - 1865-7117
SN  - 0932-0776
VL  - 59.2004
SP  - 277
EP  - 280
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -