TY  - JOUR
A1  - Hausen, Hans-Dieter
A1  - Kaim, Wolfgang
T1  - Elektronenreiche Olefine, 1. Zusammenhang zwischen Struktur, Spektroskopie und Reaktivität von Tetrakis(trimethylsilylmethyl)ethen
T1  - Electron rich olefins, 1. The relationship between structure, spectroscopy, and reactivity of tetrakis(trimethylsilylmethyl)ethene
T2  - Zeitschrift für Naturforschung, B
N2  - Crystal and molecular structure analysis of the electron rich title compound exhibits an undistorted, yet sterically shielded tetra(primary alkyl)-substituted double bond system with alternating anti-periplanar CH2SiMe3 substituents. The diastereotopic methylene protons have been located and their position correlated to the 1HNMR data and to the ESR hyperfine coupling constants of the corresponding radical cation. In contrast to the highly inert all-carbon derivative, tetraneopentylethene, the more electron-rich and more flexible organosilicon title compound reacts with bromine. Close to orthogonal arrangement between the C-C(H2)-Si planes and the ethene plane ensures effective, fourfold σ/π-hyperconjugation.
KW  - Organosilicon Compounds
KW  - Stereochemistry
KW  - ESR Spectra
KW  - Olefins
KW  - NMR Spectra
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/72189
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-721898
SN  - 1865-7117
SN  - 0932-0776
VL  - 43.1988
IS  - 1
SP  - 82
EP  - 88
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -