TY  - JOUR
A1  - Rivera, Augusto
A1  - Rojas, Jicli José
A1  - Osorio, Héctor Jairo
A1  - Ríos-Motta, Jaime
A1  - Bolte, Michael
T1  - Crystal structure of the 1:2 co-crystal of 1,3,6,8-tetraazatricyclo[4.3.1.13,8]undecane (TATU) and 4-chlorophenol (1/2)
T2  - Acta crystallographica. Section E, Crystallographic communications
N2  - In the title compound, C7H14N4·2C6H5ClO, which crystallized with two crystallographically independent 4-chloro­phenol mol­ecules and one 1,3,6,8-tetra­aza­tri­cyclo­[4.3.1.13,8]undecane (TATU) mol­ecule in the asymmetric unit, the independent components are linked by two O-H...N hydrogen bonds. The hydrogen-bond acceptor sites are two non-equivalent N atoms from the aminal cage structure, and the tricyclic system distorts by changing the C-N bond lengths. In the crystal, these hydrogen-bonded aggregates are linked into chains along the c axis by C-H...N hydrogen bonds. The crystal structure also features C-H...[pi] contacts.
KW  - TATU
KW  - co-crystalline adducts
KW  - crystal structure
KW  - hydrogen bonding
Y1  - 2016
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/42878
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-428787
UR  - https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5095853
SN  - 2056-9890
N1  - This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
VL  - 72
IS  - Pt 11
SP  - 1648
EP  - 1650
PB  - International Union of Crystallography
CY  - Chester
ER  -