TY  - JOUR
A1  - Rivera, Augusto
A1  - Pacheco, Dency Jose
A1  - Ríos-Motta, Jaime
A1  - Maldonado, Mauricio
A1  - Bolte, Michael
T1  - rac-4-Chloro-2-[({2-[(3-chloro-6-hydroxy-2,4-dimethylbenzyl)(methyl)amino]propyl}(methyl)amino)methyl]-3,5-dimethylphenol
T2  - Acta crystallographica / Section E, Structure reports online
N2  - The title compound, C23H32Cl2N2O2, a potential chiral ligand for coordination chemistry, was prepared by a two-step reaction. The molecule is located on a crystallographic centre of inversion. As a result, the methyl group bonded to the methylene group is disordered over two equally occupied positions, sharing the same site as the H atom of the chiral C atom. As a further consequence of the crystallographic centrosymmetry, the 1,2-diaminopropane unit adopts an antiperiplanar conformation and the two benzene rings are coplanar. The central chain is in an all-trans arrangement. An intramolecular O-H...N hydrogen bond makes an S(6) ring motif. A C-H...[pi] interaction links the molecules into one-dimensional chains along the [001] direction.
Y1  - 2012
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/27429
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-274295
SN  - 1600-5368
VL  - 68
IS  - o2997
PB  - Munksgaard
CY  - Copenhagen
ER  -