TY  - JOUR
A1  - Völker, G. W.
A1  - Heydtmann, Horst
T1  - Die unimolekulare thermische Spaltung von Äthylchlorid-2-d3 und Äthylchlorid-2-d1 nach einem Vierzentrenmechanismus
T2  - Zeitschrift für Naturforschung, B
N2  - The unimolecular thermal decomposition of chloroethane-2-d3 and chloroethane-2-d1 was studied in a static system at two temperatures and at pressures between 0.1 and 10 mm Hg. The rate constants for the high pressure limit were obtained from these measurements and used to calculate the Arrhenius equations. The decomposition of chloroethane-2-d3 was also studied at high conversions and yielded almost exclusively (97%) DCl and CD2CH2 as shown by mass spectrometric analysis thus proving a molecular elimination mechanism via a four-centered reaction complex.
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/74887
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-748876
SN  - 1865-7117
SN  - 0932-0776
VL  - 23.1968
IS  - 11
SP  - 1407
EP  - 1411
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -