TY  - JOUR
A1  - Maué, Paul Georg
A1  - Fenske, Dieter
T1  - Zur Reaktion von [Cp2TiCl2] und [CpTiCl3] mit E(SiMe3)2 (E = S, Se). Die Kristallstrukturen von [Cp3Ti2S2Cl], [Cp4Ti2S2Cl2], [Cp3Ti2Se2Cl] und [Cp4Ti4Se7O]
T1  - Reaction of [Cp2TiCl2] and [CpTiCl3] with E(SiMe3)2 (E = S. Se). The crystal structures of [Cp3Ti2S2Cl], [Cp3Ti2S2Cl2], [Cp3Ti2Se2Cl] and [Cp4Ti4Se7O]
T2  - Zeitschrift für Naturforschung, B
N2  - The reaction of [Cp2TiCl2 ] with E(SiMe3)2 leads to dinuclear Ti complexes. In [Cp3Ti2S2Cl] (1) and [Cp3Ti2Se2Cl] (3) two μ2 -S(Se) ligands bridge the Cp2Ti and CpTiCl units, respectively in contrast to these, [Cp4Ti2S2Cl2] (2) contains a μ2η1-S2 bridge connecting two Cp2TiCl fragments. A similar reaction of [CpTiCl3] with Se(SiMe3)2 leads to the tetranuclear cluster [Cp4Ti4Se7O] (4). 4 consists of a Ti4 -tetrahedron which encloses an oxygen atom.
KW  - X-Ray
KW  - Crystal Structure Dinuclear Ti-S and Ti-Se Complexes
KW  - Tetranuclear Ti Cluster
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/71435
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-714357
SN  - 1865-7117
SN  - 0932-0776
N1  - Teil von Maué, Paul Georg: Neue Übergangsmetallkomplexe mit Chalkogenliganden. Frankfurt (Main), Univ., Diss., 1988
VL  - 43.1988
IS  - 10
SP  - 1213
EP  - 1218
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -