TY  - JOUR
A1  - Roesky, Herbert W.
A1  - Sidiropoulos, Georg
T1  - Zur Reaktivität von Isocyanaten mit Tris(dimethylamino)arsin
T1  - The Reactivity of Isocyanates with Tris(dimethylamino)arsine
T2  - Zeitschrift für Naturforschung, B
N2  - As[N(CH3)2]3 reacts with the following isocyanates: FSO2NCO, n-C4F9SO2NCO, SO2(NCO)2 and (CH3)3SiNCO. The products which result from reaction of FSO2NCO and n-C4F9SO2NCO are the acyclic tri- and bisubstituted arsines [xxx] 
In contrast, SO2(NCO)2 and (CH3)3SiNCO form eight- and four-membered ring compounds, where the skeleton consists of the atoms As2S2N4 (3) and As2N2 (4). The new compounds were characterized by NMR and mass spectra.
KW  - Cyclic S-N-Compounds
KW  - Isocyanates
KW  - Insertion Reactions
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/71900
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-719005
SN  - 1865-7117
SN  - 0932-0776
VL  - 32.1977
IS  - 6
SP  - 628
EP  - 630
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -