TY  - JOUR
A1  - Roesky, Herbert W.
A1  - Kloker, Wolfgang
T1  - Darstellung, Eigenschaften, KMR-, IR- und Raman-Spektren von Verbindungen des Typs R-P(Se)F2, R-P(Se)FCl und R-P(Se)Cl2
T1  - Preparation, chemical properties, NMR- and vibrational spectra of compounds of the type R-P(Se)F2-, R-P(Se)FCl and R-P(Se)Cl2
T2  - Zeitschrift für Naturforschung, B
N2  - R-P(Se)F2- (R = CH3, C2H5, C3H11, C6H5, N(CH3)2, N(C2H5)2, NHSi(CH3)3) and R-P(Se)FCl-compounds (R = CH3, C2H5) can be prepared by reaction of R-P(Se)Cl2-derivatives with antimony(III)fluoride under reduced pressure. In some cases the oxidation of fluorophophines with elemental selenium is successful. The isolated compounds are colourless volatile liquids which are sensitive to air and moisture. The chemical properties are described.
1H-, 19F-, 31P-NMR-, IR- and Raman-spectroscopic data are given. Main stretching frequencies are discussed by comparison with similar oxygen- and sulphur-compounds.
KW  - Seleniumphosphoryl-compounds
KW  - NMR -spectra
KW  - IR-spectra
KW  - Raman-spectra
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/76119
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-761195
SN  - 1865-7117
SN  - 0932-0776
VL  - 28
IS  - 11-12
SP  - 607
EP  - 706
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -