TY  - JOUR
A1  - Fenske, Dieter
A1  - Böhm, Eberhard
A1  - Dehnicke, Kurt
A1  - Strähle, Joachim
T1  - N-Trimethylsilyl-iminotriphenylphosphoran-Kupfer(II)-chlorid, [Me3SiNPPh3·CuCl2]2. Synthese und Kristallstruktur
T1  - N-trimethylsilyl-iminotriphenylphosphorane copper(II) chloride, [Me3SiNPPh3·CuCl2]2. Synthesis and crystal structure
T2  - Zeitschrift für Naturforschung, B
N2  - The title compound has been prepared by the reaction of N-trimethylsilyl-iminotriphenylphos-phorane with copper(II) chloride in boiling CCl4 /C2H5OH, and forms moisture sensitive crystals, which are green in transmittance and black in reflexion. [Me3SiNPPh3 · CuCl2 ] 2 was characterized by its IR spectrum as well as by a crystal structure determination (4197 observed, independent reflexions, R = 0.049). The lattice dimensions are at 20 °C: a = 1102.7. b = 1407.3. c = 1560.2 pm; β = 94.27°; space group P21/n with two formula units in the unit cell. The complex consists of centrosymmetric, dimeric molecules with a planar Cu2 Cl2 ring (Cu-CI bond lengths 229 and 231 pm). A terminally bonded CI atom (Cu-CI = 221 pm) and the N atom of the Me3SiNPPh3 ligand (Cu-N = 198.5 pm) complete the coordination number four of the nearly planar surroundings of the Cu atoms.
KW  - N-Trimethylsilyl-iminotriphenylphosphorane Copper(II) Chloride
KW  - Synthesis
KW  - IR Spectra
KW  - Crystal Structure
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/71439
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-714392
SN  - 1865-7117
SN  - 0932-0776
VL  - 43.1987
IS  - 1
SP  - 1
EP  - 4
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -