TY  - JOUR
A1  - Neidl, Cornelia
A1  - Stauff, Joachim
T1  - Photodecomposition of 1,2-dioxetanes
T2  - Zeitschrift für Naturforschung, B
N2  - Diadamantyldioxetane, trim ethyldioxetane and tetram ethyldioxetane were photolyzed b y light of A > 260 nm . The spectral distribution o f the quanta emitted during photoinduced decom position of dioxatenes was found to be different from fluorescence and phosphorescence o f ketones. Flash photolysis experim ents showed the absorption of an short-lived interm ediate. It was concluded, therefore, that photolysis o fdioxetanes is not a concerted process but involves at least one precursor o f the final product ketone.
KW  - 1,2-D ioxetanes
KW  - Photodecom position
KW  - Luminescence Spectra Flash Photolysis
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/71903
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-719031
SN  - 1865-7117
SN  - 0932-0776
VL  - 32.1977
IS  - 9
SP  - 1102
EP  - 1103
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -