TY  - JOUR
A1  - Tschmutowa, Galina
A1  - Bock, Hans
T1  - Photoelektronen-Spektren und Moleküleigenschaften, LXIII. Ionisierungsenergien von Phenyl-Methyl-Tellurid und Vergleich der Effekte von Sauerstoff-, Schwefel-, Selen- und Tellur-Substituenten auf das Benzol-π-System
T1  - Photoelectron Spectra and Molecular Properties, LXIII. Ionization Energies of Phenyl Methyl Telluride and Comparison of Effects of Oxygen, Sulphur, Selenium and Tellurium Substituents on the Benzene π System
T2  - Zeitschrift für Naturforschung, B
N2  - The photoelectron spectrum of H5C6-Te-CH3 displays in its low energy region overlapping bands of gas-phase conformers. Depending on the dihedral angle between the plane of the phenyl ring and the tellurium lone pair, the π conjugation amounts to only 0.1 eV and 0.3 eV, respectively. These values are compared to the considerably larger ones found for the analogous phenyl derivatives H5C6-X-CH3 with X = O, S and Se.
KW  - Tellurium Organic Compounds
KW  - Photoelectron Spectra
KW  - π Conjugation
KW  - Conformers
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/76911
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-769116
SN  - 1865-7117
SN  - 0932-0776
VL  - 31
IS  - 12
SP  - 1611
EP  - 1615
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -