TY  - JOUR
A1  - Tschmutowa, Galina
A1  - Bock, Hans
T1  - Photoelektronenspektren und Moleküleigenschaften, LXIV. Dimethyldiselenid - ein Beispiel für die Wechselwirkung zwischen benachbarten Elektronenpaaren
T1  - Photoelectron Spectra and Molecular Properties, LXIV. Dimethyldiselenide - an Example for the Interaction between Adjacent Electron Pairs
T2  - Zeitschrift für Naturforschung, B
N2  - The well-resolved helium(I) photoelectron spectrum of H3C-Se—Se-CH3 exhibits distinct bands corresponding to 11 of the total 13 valence electron ionizations. The unequivocal assignment is supported by EHMO calculations including spin/orbit coupling. The two selenium lone pair ionizations differ by 0.23 eV; a split observed also for dimethyl disulfide and discussed within a general model for interactions between adjacent lone pairs.
KW  - Selenium Organic Compounds
KW  - Photoelectron Spectra
KW  - Electron Pair Interaction
KW  - Gas Phase Conformation
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/76909
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-769099
SN  - 1865-7117
SN  - 0932-0776
VL  - 31
IS  - 12
SP  - 1616
EP  - 1620
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -