My2-Acetone-diacetone[my3-tris­(trifluoro­meth­yl)methano­lato]bis­[my2-tris­(trifluoro­meth­yl)methano­lato]trilithium

  • The title compound, [Li3(C4F9O)3(C3H6O)3], features an open Li/O cube with an Li ion missing at one corner. Three of the four bridging O atoms of the cube carry a fluorinated tert-butyl residue, whereas the fourth is part of an acetone mol­ecule. Two of the Li atoms are further bonded to a non-bridging acetone mol­ecule. Two of the lithium ion coordination geometries are very distorted LiO4 tetra­hedra; the third could be described as a very distorted LiO3 T-shape with two distant F-atom neighbours. The Li[cdots, three dots, centered]Li contact distances for the three-coordinate Li+ ion [2.608 (14) and 2.631 (12) Å] are much shorter that the contact distance [2.940 (13) Å] between the tetra­hedrally coordinated species.

Download full text files

Export metadata

Additional Services

Share in Twitter Search Google Scholar
Metadaten
Author:Hannes Vitze, Hans-Wolfram LernerGND, Michael BolteORCiD
URN:urn:nbn:de:hebis:30-108335
DOI:https://doi.org/10.1107/S1600536810044685
Parent Title (English):Acta crystallographica / Section E, Structure reports online
Document Type:Article
Language:English
Year of Completion:2010
Year of first Publication:2010
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2011/06/17
Volume:66
Issue:m1527
Note:
Copyright © Vitze et al. 2010 This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
Source:Acta Crystallographica Section E: Structure Reports Online, 66(Pt 12): m1527. ; doi: 10.1107/S1600536810044685
HeBIS-PPN:272725749
Institutes:Biochemie, Chemie und Pharmazie / Biochemie und Chemie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Sammlungen:Universitätspublikationen
Licence (German):License LogoDeutsches Urheberrecht