The role of low-volatility organic compounds in initial particle growth in the atmosphere

  • About half of present-day cloud condensation nuclei originate from atmospheric nucleation, frequently appearing as a burst of new particles near midday1. Atmospheric observations show that the growth rate of new particles often accelerates when the diameter of the particles is between one and ten nanometres2,3. In this critical size range, new particles are most likely to be lost by coagulation with pre-existing particles4, thereby failing to form new cloud condensation nuclei that are typically 50 to 100 nanometres across. Sulfuric acid vapour is often involved in nucleation but is too scarce to explain most subsequent growth5,6, leaving organic vapours as the most plausible alternative, at least in the planetary boundary layer7,8,9,10. Although recent studies11,12,13 predict that low-volatility organic vapours contribute during initial growth, direct evidence has been lacking. The accelerating growth may result from increased photolytic production of condensable organic species in the afternoon2, and the presence of a possible Kelvin (curvature) effect, which inhibits organic vapour condensation on the smallest particles (the nano-Köhler theory)2,14, has so far remained ambiguous. Here we present experiments performed in a large chamber under atmospheric conditions that investigate the role of organic vapours in the initial growth of nucleated organic particles in the absence of inorganic acids and bases such as sulfuric acid or ammonia and amines, respectively. Using data from the same set of experiments, it has been shown15 that organic vapours alone can drive nucleation. We focus on the growth of nucleated particles and find that the organic vapours that drive initial growth have extremely low volatilities (saturation concentration less than 10−4.5 micrograms per cubic metre). As the particles increase in size and the Kelvin barrier falls, subsequent growth is primarily due to more abundant organic vapours of slightly higher volatility (saturation concentrations of 10−4.5 to 10−0.5 micrograms per cubic metre). We present a particle growth model that quantitatively reproduces our measurements. Furthermore, we implement a parameterization of the first steps of growth in a global aerosol model and find that concentrations of atmospheric cloud concentration nuclei can change substantially in response, that is, by up to 50 per cent in comparison with previously assumed growth rate parameterizations.

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Author:Jasmin Tröstl, Wayne K. Chuang, Hamish Gordon, Martin Heinritzi, Chao Yan, Ugo Molteni, Lars Ahlm, Carla Frege, Federico Bianchi, Robert Wagner, Mario Simon, Katrianne Lehtipalo, Christina Williamson, Jill Craven, Jonathan DuplissyORCiD, Alexey Adamov, Joao Almeida, Anne-Kathrin Bernhammer, Martin Breitenlechner, Sophia Brilke, Antonio Dias, Sebastian Ehrhart, Richard C. Flagan, Alessandro Franchin, Claudia Fuchs, Roberto Guida, Martin Gysel, Armin Hansel, Christopher Robert Hoyle, Tuija Jokinen, Heikki Junninen, Juha Kangasluoma, Helmi Keskinen, Jaeseok Kim, Manuel Krapf, Andreas Kürten, Ari Laaksonen, Michael Joseph Lawler, Markus Leiminger, Serge Mathot, Ottmar MöhlerORCiDGND, Tuomo Nieminen, Antti Onnela, Tuukka Petäjä, Felix Piel, Pasi Miettinen, Matti P. Rissanen, Linda Rondo, Nina Sarnela, Siegfried Schobesberger, Kamalika Sengupta, Mikko Sipilä, James N. Smith, Gerhard Steiner, Antonio Tomé, Annele Virtanen, Andrea Christine Wagner, Ernest Weingartner, Daniela Wimmer, Paul M. Winkler, Penglin Ye, Kenneth S. Carslaw, Joachim CurtiusORCiD, Josef Dommen, Jasper Kirkby, Markku Kulmala, Ilona Riipinen, Douglas R. Worsnop, Neil McPherson Donahue, Urs BaltenspergerORCiDGND
Pubmed Id:
Parent Title (English):Nature
Publisher:Nature Publ. Group
Place of publication:London [u. a.]
Document Type:Article
Year of Completion:2016
Date of first Publication:2016/05/26
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2019/07/15
Tag:Atmospheric chemistry; Thermodynamics
Page Number:20
First Page:527
Last Page:531
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Institutes:Geowissenschaften / Geographie / Geowissenschaften
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 55 Geowissenschaften, Geologie / 550 Geowissenschaften
Licence (German):License LogoCreative Commons - Namensnennung 4.0