Two salts of the 6,6-difluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide anion with different cations
- The crystal structures are reported of the 6,6-difluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide (or 9,9-difluoro-10-oxa-9-boraphenanthren-9-ide) anion with two different cations, namely, potassium 6,6-difluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide, K+·C12H8BF2O−, (II), featuring a polymeric structure, and bis(tetraphenylphosphonium) bis(6,6-difluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide) acetonitrile trisolvate, 2C24H20P+·2C12H8BF2O−·3CH3CN, (III), which is composed of discrete cations, anions and acetonitrile solvent molecules linked by C—H...O, C—H...N and C—H...F hydrogen bonds. There are only minor differences in the geometrical parameters of the anions in these structures.
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| Author: | Alexandra Budanow, Hans-Wolfram LernerGND, Michael BolteORCiD |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-640819 |
| DOI: | https://doi.org/10.1107/S2056989020015066 |
| ISSN: | 2056-9890 |
| Parent Title (English): | Acta crystallographica. Section E, Crystallographic communications |
| Publisher: | International Union of Crystallography |
| Place of publication: | Chester |
| Document Type: | Article |
| Language: | English |
| Date of Publication (online): | 2020/12/01 |
| Date of first Publication: | 2020/12/01 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2021/11/08 |
| Tag: | boron; crystal structure; fluorine; potassium |
| Volume: | 76 |
| Issue: | 12 |
| Page Number: | 23 |
| First Page: | 1837 |
| Last Page: | 1840 |
| Note: | CCDC references: 2043934; 2043933 |
| HeBIS-PPN: | 489033636 |
| Institutes: | Biochemie, Chemie und Pharmazie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Open-Access-Publikationsfonds: | Biochemie, Chemie und Pharmazie |
| Licence (German): |  Creative Commons - Namensnennung 4.0 |
