Dibromidotris(dimethylamine)-magnesium(II)

  • The Mg centre in the title compound, [MgBr2(C2H7N)3], is penta­coordinated in a trigonal-bipyramidal mode with the two Br atoms in axial positions and the N atoms of the dimethyl­amine ligands in equatorial positions. The MgII centre is located on a crystallographic twofold rotation axis. The crystal structure is stabilized by N—H⋯Br hydrogen bonds. The N atom and H atoms of one dimethylamine ligand are disordered over two equally occupied positions.

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Author:Hannes Vitze, Hans-Wolfram LernerGND, Michael BolteORCiD
URN:urn:nbn:de:hebis:30-68927
DOI:https://doi.org/10.1107/S1600536809024702
ISSN:2056-9890
ISSN:1600-5368
Pubmed Id:https://pubmed.ncbi.nlm.nih.gov/21583351
Parent Title (English):Acta crystallographica. Section E, Structure reports online
Publisher:International Union of Crystallography
Place of publication:Chester
Document Type:Article
Language:English
Year of Completion:2009
Date of first Publication:2009/08/01
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2009/09/02
Volume:65
Issue:8, m888
Page Number:8
Note:
Copyright © Vitze et al. 2009. This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
Source:Acta Cryst. (2009). E65, m888 [ doi:10.1107/S1600536809024702 ]
HeBIS-PPN:217323758
Institutes:Biochemie, Chemie und Pharmazie / Biochemie und Chemie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Licence (German):License LogoCreative Commons - Namensnennung 4.0