Crystal structure of [tBuMgCl]2[MgCl2(Et2O)2]2
- The title compound, di-μ3-chlorido-tetra-μ2-chlorido-tetrakis(diethyl ether-κO)bis(1,1-dimethylethyl)tetramagnesium, [Mg4(C4H9)2Cl6(C4H10O)4], features an Mg4Cl6 open-cube cluster. The two four-coordinate Mg2+ ions show an almost tetrahedral coordination, whereas the two six-coordinate Mg2+ ions have their ligands in an octahedral environment. The Mg—Cl bond lengths differ depending on the coordination number (2 or 3) of the bridging μ-Cl− ligands. There are few comparable structures deposited in the Cambridge Structural Database.
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| Author: | Maurice MetzlerORCiD, Michael BolteORCiD, Matthias WagnerORCiD, Hans-Wolfram LernerORCiDGND |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-757701 |
| DOI: | https://doi.org/10.1107/S2056989023002190 |
| ISSN: | 2056-9890 |
| Parent Title (English): | Acta Crystallographica. Section E, Crystallographic communications |
| Publisher: | International Union of Crystallography |
| Place of publication: | Chester |
| Document Type: | Article |
| Language: | English |
| Year of Completion: | 2023 |
| Year of first Publication: | 2023 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2023/09/18 |
| Tag: | Grignard reagent; crystal structure; open-cube cluster |
| Volume: | 79 |
| Issue: | 4 |
| Page Number: | 13 |
| First Page: | 341 |
| Last Page: | 344 |
| HeBIS-PPN: | 513119086 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - CC BY - Namensnennung 4.0 International |
