Dynamic nuclear polarization for sensitivity enhancement in modern solid-state NMR
- The field of dynamic nuclear polarization has undergone tremendous developments and diversification since its inception more than 6 decades ago. In this review we provide an in-depth overview of the relevant topics involved in DNP-enhanced MAS NMR spectroscopy. This includes the theoretical description of DNP mechanisms as well as of the polarization transfer pathways that can lead to a uniform or selective spreading of polarization between nuclear spins. Furthermore, we cover historical and state-of-the art aspects of dedicated instrumentation, polarizing agents, and optimization techniques for efficient MAS DNP. Finally, we present an extensive overview on applications in the fields of structural biology and materials science, which underlines that MAS DNP has moved far beyond the proof-of-concept stage and has become an important tool for research in these fields.
Author: | Aany Sofia Lilly Thankamony, Johannes J. Wittmann, Monu Kaushik, Björn Corzilius |
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URN: | urn:nbn:de:hebis:30:3-466423 |
DOI: | https://doi.org/10.1016/j.pnmrs.2017.06.002 |
ISSN: | 1873-3301 |
ISSN: | 0079-6565 |
Pubmed Id: | https://pubmed.ncbi.nlm.nih.gov/29157490 |
Parent Title (English): | Progress in nuclear magnetic resonance spectroscopy |
Publisher: | Elsevier Science |
Place of publication: | Amsterdam [u. a.] |
Contributor(s): | Geoffrey Bodenhausen, Beat Meier |
Document Type: | Article |
Language: | English |
Year of Completion: | 2017 |
Date of first Publication: | 2017/07/23 |
Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
Release Date: | 2018/09/20 |
Volume: | 102-103 |
Page Number: | 76 |
First Page: | 120 |
Last Page: | 195 |
Note: | © 2017 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). |
HeBIS-PPN: | 437862380 |
Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
Wissenschaftliche Zentren und koordinierte Programme / Zentrum für Biomolekulare Magnetische Resonanz (BMRZ) | |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
Sammlungen: | Universitätspublikationen |
Licence (German): | Creative Commons - Namensnennung-Nicht kommerziell - Keine Bearbeitung 4.0 |