4-[3-(Isonicotino-yloxy)propoxycarbon-yl]pyridinium diiodidoargentate(I)
- The structure of the title compound, (C15H15N2O4)[AgI2], consists of an organic 4-[3-(isonicotinoyloxy)propoxycarbonyl]pyridinium cation which has a gauche–gauche (O/C/C/C—O/C/C/C or GG’) conformation and lies on a twofold rotation axis, which passes through the central C atom of the aliphatic chain, and an inorganic [AgI2]− anion. In the complex anion, the Ag+ cation is bound to two I− anions in a linear geometry. The anion was modelled assuming disorder around a crystallographic inversion centre near the location of the Ag+ cation. The crystal packing is stabilized by a strong intermolecular N—H[cdots, three dots, centered]N hydrogen bond, which links the cations into zigzag chains with graph-set notation C(16) running along the face diagonal of the ac plane. The N-bound H atom is disordered over two equally occupied symmetry-equivalent sites, so that the molecule has a pyridinium ring at one end and a pyridine ring at the other.
Author: | Javier Vallejos, Iván Brito, Alejandro Cárdenas, Michael BolteORCiD, Matías López-Rodríguez |
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URN: | urn:nbn:de:hebis:30:3-252891 |
DOI: | https://doi.org/10.1107/S1600536811047295 |
ISSN: | 1600-5368 |
Pubmed Id: | https://pubmed.ncbi.nlm.nih.gov/22199556 |
Parent Title (English): | Acta crystallographica / Section E, Structure reports online |
Publisher: | Munksgaard |
Place of publication: | Copenhagen |
Document Type: | Article |
Language: | English |
Date of Publication (online): | 2011/11/12 |
Date of first Publication: | 2011/11/12 |
Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
Release Date: | 2012/06/25 |
Volume: | 67 |
Issue: | m1759–m1760 |
Page Number: | 11 |
HeBIS-PPN: | 35758595X |
Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
Sammlungen: | Universitätspublikationen |
Licence (German): | Creative Commons - Namensnennung 3.0 |