Mikrowellenspektrum, Struktur und interne Rotation von 2,2,2-Trifluor-1,1,1-trichloräthan
- The microwave spectrum of CF3CCl3 has been investigated in the region from 15 to 40 GHz. A least squares analysis of the rotational constants gave the following structural parameters: dC–C= (1,5394 ± 0,001) A, dC–F= (1,330 ±0,001) A, dC-Cl = (1,7710 ± 0,0009) A, ∢ C—C—F = (109,55 ± 0,25) °, ∢ C—C—Cl= (109,55 ± 0,25) °. The splitting of the torsional satellite may be explained by the theory of KOEHLER and DENNISON.
Author: | Reimer Holm, Michael MitzlaffGND, Hermann HartmannGND |
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URN: | urn:nbn:de:hebis:30:3-740690 |
DOI: | https://doi.org/10.1515/zna-1968-0714 |
ISSN: | 1865-7109 |
Parent Title (German): | Zeitschrift für Naturforschung, A |
Publisher: | Verlag der Zeitschrift für Naturforschung |
Place of publication: | Tübingen |
Document Type: | Article |
Language: | German |
Date of Publication (online): | 2014/06/02 |
Year of first Publication: | 1968 |
Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
Release Date: | 2023/06/23 |
Volume: | 23 |
Issue: | 7 |
Page Number: | 3 |
First Page: | 1040 |
Last Page: | 1042 |
HeBIS-PPN: | 510489346 |
Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
Sammlungen: | Universitätspublikationen |
Licence (German): | Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |