Zur Stereochemie der Bisaboloide aus Matricaria chamomilla L.
On the stereochemistry of the bisaboloids from matricaria chamomilla L.
- The stereochemistry of the bisaboloids in chamomile-with the exception of bisabolol-oxide C-has been elucidated. The in-vitro-examination of the mutual convertibilities of some bisaboloids gave evidence for the stereochemical accordance of the common chiral centres of all the bisaboloids. The absolute configurations of the remaining third asymmetric carbon atoms in bisabololoxide A and B have been determined by NMR spectrometric studies in comparison with their unnatural semisynthetic epimers. All the stereogenic centres of the bisabololoxides A and B, of (-)-α-bisabolol and of bisabolonoxide A turn out to be S-configurated.
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| Author: | Elmar FlaskampGND, Gerhard NonnenmacherGND, Gottfried ZimmermannGND, Otto Isaac |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-719511 |
| DOI: | https://doi.org/10.1515/znb-1981-0822 |
| ISSN: | 1865-7117 |
| ISSN: | 0932-0776 |
| Parent Title (German): | Zeitschrift für Naturforschung, B |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | German |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 1981 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2024/01/09 |
| Tag: | 13C NMR Spectra; Bisaboloids; Matricaria chamomilla L; Shift-Reagents |
| Volume: | 36.1981 |
| Issue: | 8 |
| Page Number: | 8 |
| First Page: | 1023 |
| Last Page: | 1030 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| 5 Naturwissenschaften und Mathematik / 57 Biowissenschaften; Biologie / 570 Biowissenschaften; Biologie | |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
