Reaktion von Tetraschwefeltetranitrid mit Rhenium(VII)-chloronitrid. Die Kristallstruktur von [Ph4As+]2[Cl4 Re(NS)(NSCl)2-]·CH2Cl2
Reaction of tetrasulfurtetranitride with rhenium(VII)-chloronitride. The crystal structure of [Ph4As+]2[Cl4 Re(NS)(NSCl)2-]·CH2Cl2
- The synthesis of [Ph4As+]2[Cl4Re(NS)(NSCl)2-] · CH2Cl2 (4) from the reaction of S4N4, Cl4ReN, and Ph4AsCl is reported. CH2Cl2 is used as solvent. The reaction of S4N4 with Re2Cl10 similarly leads to the salt [Ph4As+][Cl2ReNS-] (5) in a smaller yield. 4 crystallizes in the triclinic space group P1̅ with Z = 2, a - 10.434(2), b = 12.1454(6), c = 21.125(2) Å, a = 81.210(6), β = 86.70(1), γ = 76.624(8)°.
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| Author: | Jens Anhaus, Zafar A. Siddiqi, Herbert W. RoeskyORCiDGND, Jan W. Bats, Yalcin Elerman |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-719884 |
| DOI: | https://doi.org/10.1515/znb-1985-0609 |
| ISSN: | 1865-7117 |
| ISSN: | 0932-0776 |
| Parent Title (German): | Zeitschrift für Naturforschung, B |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | German |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 1985 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2024/01/10 |
| Tag: | Crystal Structure; Rhenium(VII); Thionitrosyl Complexes |
| Volume: | 40.1985 |
| Issue: | 6 |
| Page Number: | 5 |
| First Page: | 740 |
| Last Page: | 744 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
