Radikalionen, 69 [1, 2]. Die elektrochemische Reduktion aromatischer Nitro-Verbindungen in aprotischer Lösung
Radical ions, 69 [1, 2]. The electrochemical reduction of aromatic nitro compounds in aprotic solution
- The reduction potentials of 40 aromatic nitro compounds Rπ(NO2)n with Rπ = benzene, naphthalene, anthracene, fluorene and carbazole and n = 1 to 4 nitro groups are determined by cyclic voltammetry in DMF under aprotic conditions. The perturbation by the strongly electron accepting substituents can be rationalized via correlation with HMO eigenvalues. Based on reversibility criteria, the electrochemical behaviour is discussed and the compounds are classified with respect to reversible or irreversible one-electron transfer as well as up to 4 (quasi)-reversible reduction steps. The CV data measured can be used to predict redox reactions of aromatic nitro compounds in inert solvents.
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| Author: | Hans BockGND, Ulrike Lechner-KnoblauchGND |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-719938 |
| DOI: | https://doi.org/10.1515/znb-1985-1108 |
| ISSN: | 1865-7117 |
| ISSN: | 0932-0776 |
| Parent Title (German): | Zeitschrift für Naturforschung, B |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | German |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 1985 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2024/01/11 |
| Tag: | Aromatic Nitro Compounds; Cyclic Voltammetry; Electron Transfer |
| Volume: | 40.1985 |
| Issue: | 11 |
| Page Number: | 13 |
| First Page: | 1463 |
| Last Page: | 1475 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
