Zur Reaktion von [(η3-C4H7)PdCl]2 mit Se(SiMe3)2. Die Kristallstruktur von [(η3-C4H7)6Pd6Se3]
Reaction of [(η3-C4H7)PdCl]2 with Se(SiMe3)2. The crystal structure of [(η3-C4H7)6Pd6Se3]
- [(η3-C4H7)PdCl]2 reacts with Se(SiMe3)2 to form [(η3-C4H7)6Pd6Se3] (1). 1 has been characterized by X-ray crystal structure analysis. It contains a distorted trigonal prismatic Pd6-cluster. Three faces of the Pd-prism are occupied by μ4-Se ligands. 1 crystallizes in the space group Pnma with 4 formula units per unit cell. The lattice constants at 200 K are: a = 1175.1(8), b = 1611.4(12), c = 1720.3(12) pm.
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| Author: | Dieter FenskeGND, Achim Hollnagel, Kurt MerzweilerORCiDGND |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-721882 |
| DOI: | https://doi.org/10.1515/znb-1988-0525 |
| ISSN: | 1865-7117 |
| ISSN: | 0932-0776 |
| Parent Title (German): | Zeitschrift für Naturforschung, B |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | German |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 1988 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2024/01/18 |
| Tag: | Crystal Structure of [(η3-C4H7)6Pd6Se3]; Synthesis; Trigonal Prismatic Pd-Se Cluster; X-Ray |
| Volume: | 43.1988 |
| Issue: | 5 |
| Page Number: | 3 |
| First Page: | 634 |
| Last Page: | 636 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
