Die unimolekulare thermische Spaltung von Äthylchlorid-2-d3 und Äthylchlorid-2-d1 nach einem Vierzentrenmechanismus
- The unimolecular thermal decomposition of chloroethane-2-d3 and chloroethane-2-d1 was studied in a static system at two temperatures and at pressures between 0.1 and 10 mm Hg. The rate constants for the high pressure limit were obtained from these measurements and used to calculate the Arrhenius equations. The decomposition of chloroethane-2-d3 was also studied at high conversions and yielded almost exclusively (97%) DCl and CD2CH2 as shown by mass spectrometric analysis thus proving a molecular elimination mechanism via a four-centered reaction complex.
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| Author: | G. W. Völker, Horst HeydtmannGND |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-748876 |
| DOI: | https://doi.org/10.1515/znb-1968-1103 |
| ISSN: | 1865-7117 |
| ISSN: | 0932-0776 |
| Parent Title (German): | Zeitschrift für Naturforschung, B |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | German |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 1968 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2024/02/07 |
| Volume: | 23.1968 |
| Issue: | 11 |
| Page Number: | 5 |
| First Page: | 1407 |
| Last Page: | 1411 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| 5 Naturwissenschaften und Mathematik / 57 Biowissenschaften; Biologie / 570 Biowissenschaften; Biologie | |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
