Filtern
Erscheinungsjahr
- 2022 (1) (entfernen)
Dokumenttyp
Sprache
- Englisch (1) (entfernen)
Volltext vorhanden
- ja (1) (entfernen)
Gehört zur Bibliographie
- nein (1)
Schlagworte
- hydrogen bonding (1) (entfernen)
Institut
- Biochemie und Chemie (1) (entfernen)
The title compound, C8H16N4·2C11H16O, was synthesized from the corresponding sterically crowded phenol by treatment with the aminal cage polyamine. Single-crystal X-ray diffraction structural analysis revealed the three-molecule aggregate to crystallize in the monoclinic space group P2/c with one half of a 1,3,6,8-tetraaztricyclo[4.4.1.13,8]dodecane (TATD) molecule and one 2-tert-butyl-4-methylphenol molecule per asymmetric unit. The crystal structure features intermolecular O—H...N and C—H...O hydrogen bonds, as well as intermolecular C—H...π interactions.