Universitätspublikationen
Filtern
Erscheinungsjahr
- 2021 (1)
Dokumenttyp
Sprache
- Englisch (1) (entfernen)
Volltext vorhanden
- ja (1) (entfernen)
Gehört zur Bibliographie
- nein (1)
Schlagworte
- DNP in solids (1) (entfernen)
Institut
Mixed-valence compounds as polarizing agents for overhauser dynamic nuclear polarization in solids
(2021)
Herein, we investigate a novel set of polarizing agents—mixed-valence compounds—by theoretical and experimental methods and demonstrate their performance in high-field dynamic nuclear polarization (DNP) NMR experiments in the solid state. Mixed-valence compounds constitute a group of molecules in which molecular mobility persists even in solids. Consequently, such polarizing agents can be used to perform Overhauser-DNP experiments in the solid state, with favorable conditions for dynamic nuclear polarization formation at ultra-high magnetic fields.