TY  - JOUR
A1  - Bats, Jan W.
A1  - Gomes-Jelonek, Jessica
A1  - Doppiu, Angelino
A1  - Hashmi, A. Stephen K.
T1  - Dichlorido(3-phenylindenylidene)bis(triphenylphosphane)ruthenium(II) tetrahydrofuran disolvate
T2  - Acta crystallographica. Section E, Structure reports online
N2  - The RuII atom in the title compound, [RuCl2(C15H10)(C18H15P)2]·2C4H8O, has a distorted square-pyramidal conformation. The P and Cl atoms are at the base of the pyramid and the Ru-Cindenyl­idene bond is in the axial position. The two Cl ligands and the two phosphane ligands are in trans positions. The Cl-Ru-Cl and P-Ru-P angles are 157.71 (2) and 166.83 (2)°, respectively. The two independent tetra­hydro­furan (THF) solvent mol­ecules are disordered. One THF mol­ecule was refined using a split-atom model. The second THF mol­ecule was accounted for by using program PLATON/SQUEEZE [Spek (2009). Acta Cryst. D65, 148-155]. The molecular conformation shows three intramolecular C-H...Cl contacts and two C-H...[pi] interactions while the crystal packing features an intermolecular C-H...Cl contact and two very weak intermolecular C-H...[pi] contacts.
Y1  - 2011
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/75819
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-758190
SN  - 1600-5368
VL  - 67
IS  - 6
SP  - m723
EP  - m724
PB  - International Union of Crystallography
CY  - Chester
ER  -