TY  - JOUR
A1  - Fenske, Dieter
A1  - Meyer, J.
A1  - Merzweiler, Kurt
T1  - Zur Reaktion von PhSSiMe3 mit [CoCl2(PPh3)2] und (NBu4)[CoCl3(PPh3)]. Die Kristallstrukturen von (NBu4)2[Co4(SPh)6Cl4], [Co4(SPh)6Cl2(POPh3)(PPh3)] und (NBu4) [Mn2(SPh)3(CO)6]
T1  - Reaction of PhSSiMe3 with [CoCl2(PPh3)2] and (NBu4)[CoCl3(PPh3)]. The crystal structures of (NBu4)2[Co4(SPh)6Cl4], [Co4(SPh)6CL(POPh3)(PPh3)] and (NBu4)[Mn2(SPh)3(CO)6]
T2  - Zeitschrift für Naturforschung, B
N2  - (NBu4)2[Co4(SPh)6Cl4] (1) and [Co4(SPh)6CU(PPh3)2] (2) are prepared by the reaction of (NBu4)[CoCl3(PPh3)] and [CoCl2(PPh3)2] with PhSSiMe3 in toluene solution. The overall description of the Co4S6Cl4 core is that o f a nearly regular Co4-tetrahedron inscribed in an irregular octahedron of the bridging S atoms resulting in an “adamantane” type cage. 1 reacts with Na[Mn(CO)5] to form the dinuclear complex (NBu4)[Mn2(SPh)3(CO)6] (4). Each Mn atom is bound to three CO and three μ2-SPh ligands. The Mn-Mn contact (318.5 pm) does not indicate metal-metal bonding.
KW  - X-Ray Crystal Structures of Co- and Mn-Clusters
KW  - Thiolate Ligands
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/79969
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-799697
SN  - 1865-7117
SN  - 0932-0776
VL  - 42.1987
IS  - 9
SP  - 1207
EP  - 1211
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -