TY  - JOUR
A1  - Dobrzańska, Liliana
A1  - Julius, Gerrit R.
A1  - Stander-Grobler, Elzet
A1  - Burger, Yolanda
A1  - Nogai, Stefan Dietrich
A1  - Cronje, Stephanie
A1  - Raubenheimer, Helgard G.
T1  - Remote and α-thio carbene complexes derived from an oxazolinylsubstituted thiophene
T2  - Zeitschrift für Naturforschung, B
N2  - Transmetallation and oxidative substitution were utilized to prepare examples of group 14, group 6 and group 10 complexes from lithiated or chlorinated 4,4-dimethyl-2-(2-thienyl) oxazoline or its N-alkylated analogs. Two of the product types (2and 5) can be classified as a-thio or remote carbene complexes, depending on the position (3- or 5-) of attachment to the substituted thiophene ring. Spectroscopic measurements as well as crystal and molecular structure determinations clarified the bonding within the new compounds.
KW  - Carbene Complexes
KW  - Thienylidene Complexes
KW  - remote Carbenes
KW  - Chromium
KW  - Palladium
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/79979
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-799794
SN  - 1865-7117
SN  - 0932-0776
VL  - 67.2012
IS  - 6
SP  - 509
EP  - 518
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -