TY  - JOUR
A1  - Lerner, Hans-Wolfram
A1  - Sänger, Inge
A1  - Bolte, Michael
A1  - Wagner, Matthias
T1  - Thermolysereaktionen der donorfreien Silanimine tBu2Si=N-SiRtBu2 (R = tBu, Ph)
T1  - Thermolysis reactions of donor-free silanimines tBu2Si=N-SiRtBu2 (R = tBu, Ph)
T2  - Zeitschrift für Naturforschung, B
N2  - The donor-free silanimines tBu2Si=N-SiRtBu2 (R = tBu, Ph), which are prepared from tBu2ClSiN3 and NaSiRtBu2 at −78 ◦C inBu2O, decompose in benzene at room temperature with the formation of isobutene. Products of ene reactions of isobutene and tBu2Si=N-SiRtBu2 (R = tBu, Ph) are formed. X-Ray quality crystals of H2C=C(CH2SitBu2-NH-SiPhtBu2)2 (monoclinic, space group C2/c, Z = 4) were grown from a benzene solution at ambient temperature, whereas single crystals of H2C=C(CH2SitBu2-NH-SitBu3)2 (monoclinic, space group P21, Z = 2) were obtained by recrystallization from THF.
KW  - SiN Double Bond
KW  - Silanimine
KW  - Ene Reaction
KW  - X-Ray Structure Analysis
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/79973
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-799738
SN  - 1865-7117
SN  - 0932-0776
VL  - 65.2010
IS  - 1
SP  - 72
EP  - 78
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -