TY  - JOUR
A1  - Kaim, Wolfgang
T1  - Koordinationsverbindungen des reduzierten Pyrazins mit Alkylderivaten von Bor, Aluminium, Gallium und Indium
T1  - Coordination complexes of reduced pyrazine and alkyl derivatives of boron, aluminum, gallium, and indium
T2  - Zeitschrift für Naturforschung, B
N2  - The alkyls MR3 (M = B, AI, Ga, In) react with pyrazine (Pz) and sodium in THF to yield persistent radical complexes Pz(MR2)2 · +MR4- (1). Use of TIR3 leads to rapid deposition of thallium metal. The formation of these ionic complexes 1 is the result of MR3 dissociation into +MR2 and -MR4 ions. All radicals have been identified and characterized by ESR; the data reveal the influence of  back bonding in the boron derivative.
KW  - Pyrazine
KW  - Alkali Metal Reduction
KW  - Group III Alkyls
KW  - Radical Complexes
KW  - ESR Spectra
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/71948
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-719483
SN  - 1865-7117
SN  - 0932-0776
VL  - 36.1981
IS  - 6
SP  - 677
EP  - 682
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -