TY  - JOUR
A1  - Gurinov, Andrei
A1  - Sieland, Benedikt
A1  - Kuzhelev, Andrey
A1  - Elgabarty, Hossam
A1  - Kühne, Thomas D.
A1  - Prisner, Thomas
A1  - Paradies, Jan H. H.
A1  - Baldus, Marc
A1  - Ivanov, Konstantin L.
A1  - Pylaeva, Svetlana
T1  - Mixed-valence compounds as polarizing agents for overhauser dynamic nuclear polarization in solids
T2  - Angewandte Chemie : International edition
N2  - Herein, we investigate a novel set of polarizing agents—mixed-valence compounds—by theoretical and experimental methods and demonstrate their performance in high-field dynamic nuclear polarization (DNP) NMR experiments in the solid state. Mixed-valence compounds constitute a group of molecules in which molecular mobility persists even in solids. Consequently, such polarizing agents can be used to perform Overhauser-DNP experiments in the solid state, with favorable conditions for dynamic nuclear polarization formation at ultra-high magnetic fields.
KW  - ab initio calculations
KW  - DNP in solids
KW  - mixed valence compounds
KW  - molecular dynamics
KW  - Overhauser effect
Y1  - 2021
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/72571
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-725715
SN  - 1521-3773
N1  - This work has been supported by iNEXT-Discovery, grant number 871037, funded by the Horizon 2020 program of the European Commission. Open access funding enabled and organized by Projekt DEAL.
VL  - 60
IS  - 28
SP  - 15371
EP  - 15375
PB  - Wiley-VCH
CY  - Weinheim
ER  -