TY  - JOUR
A1  - Roesky, Herbert W.
A1  - Aramaki, Minoru
A1  - Schönfelder, Lothar
T1  - N-Sulfonylsulfimide
T1  - N-Sulfonylsulfimides
T2  - Zeitschrift für Naturforschung, B
N2  - (CF3SO2NSO2)2 (1), a compound with a four-membered ring, was prepared from CF3SO2NSO and SO3. 1 as well as (FSO2NSO2)2 form 1:1 adducts with S4N4 , pyridine and pyridine carbonitrile-4 (2a-2f). By comparison with FSO2NCOS4N4 it was shown that a dipolar type of addition had occured. In contrast the reaction of 1 and (FSO2NSO2)2 with aromatic nitriles yields 1:2 cycloaddition products (3a-3g) which were characterized on the basis of mass spectra. The six-membered rings of 4a-4b which contain carbon, nitrogen and sulfur atoms were obtained from the reaction of isocyanates with (FSO2NSO2)2 or (CF3SO2NSO2)2. 4-BrC6H4NCO and SO3 react in a similar way to yield 5. The starting materials are extremely sensitive to moisture while most of the adducts can be handled in open air without decomposition.
KW  - N-Sulfonylamide
KW  - Fluorine-Sulfur-Nitrogen Compounds
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/71924
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-719247
SN  - 1865-7117
SN  - 0932-0776
VL  - 33.1978
IS  - 10
SP  - 1072
EP  - 1076
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -