TY  - JOUR
A1  - Flaskamp, Elmar
A1  - Nonnenmacher, Gerhard
A1  - Zimmermann, Gottfried
A1  - Isaac, Otto
T1  - Zur Stereochemie der Bisaboloide aus Matricaria chamomilla L.
T1  - On the stereochemistry of the bisaboloids from matricaria chamomilla L.
T2  - Zeitschrift für Naturforschung, B
N2  - The stereochemistry of the bisaboloids in chamomile-with the exception of bisabolol-oxide C-has been elucidated. The in-vitro-examination of the mutual convertibilities of some bisaboloids gave evidence for the stereochemical accordance of the common chiral centres of all the bisaboloids. The absolute configurations of the remaining third asymmetric carbon atoms in bisabololoxide A and B have been determined by NMR spectrometric studies in comparison with their unnatural semisynthetic epimers. All the stereogenic centres of the bisabololoxides A and B, of (-)-α-bisabolol and of bisabolonoxide A turn out to be S-configurated.
KW  - Matricaria chamomilla L
KW  - Bisaboloids
KW  - 13C NMR Spectra
KW  - Shift-Reagents
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/71951
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-719511
SN  - 1865-7117
SN  - 0932-0776
VL  - 36.1981
IS  - 8
SP  - 1023
EP  - 1030
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -